PERBANDINGAN KARAKTERISTIK FISIKOKIMIA ANTARA COCOA BUTTER ALTERNATIVE (CBA) DENGAN LEMAK KAKAO UNTUK PENGEMBANGAN STANDAR NASIONAL INDONESIA
Abstract
Cocoa butter alternative (CBA) atau alternatif lemak kakao memegang peranan penting dalam industri pengolahan cokelat atau konfeksioneri. CBA terdiri dari Cocoa Butter Equivalents (CBE), Cocoa Butter Replacers (CBR), Cocoa Butter Substitutes (CBS) yang terbagi berdasarkan komposisi kimia dan kompatibilitas dengan lemak kakao. Belum ada standar nasional dan internasional yang mengatur dan membedakan karakteristik ketiga produk tersebut. Tujuan penelitian ini adalah untuk mengetahui karakteristik CBE, CBR dan CBS dan dianalisis untuk pengembangan konsep Rancangan Standar Nasional Indonesia (RSNI) Alternatif Lemak Kakao. Metode penelitian adalah sampling dan membeli produk CBE, CBR dan CBS ke industri-industri. Analisis terhadap CBE, CBR dan CBS dilakukan untuk mengetahui karakteristiknya serta membandingkannya dengan SNI 3748:2009 Lemak Kakao. Parameter mutu yang dianalisis adalah titik leleh, kadar air, kadar asam lemak bebas, bilangan peroksida, bilangan iod, dan asam lemak trans. Hasil analisis menunjukkan bahwa CBE, CBR, CBE mempunyai kisaran rerata titik leleh sebesar 18,5-34,11 °C, kadar air 0,12-0,17%, kadar asam lemak bebas 0,06-0,10%, bilangan peroksida 0,21-2,65 mek O2/kg, bilangan iod 2,15-38,7 gram I2/100 g, dan asam lemak trans 0,4-0,11%. Parameter titik leleh, kadar air, kadar asam lemak bebas, bilangan peroksida, dan bilangan iod CBE, CBR dan CBS memenuhi semua syarat mutu SNI 3748:2009 Lemak Kakao. Nilai asam lemak trans CBA memenuhi syarat WHO (2010). Konsep RSNI Alternatif Lemak Kakao (CBA) yang diusulkan berdasarkan analisis tersebut adalah titik leleh 32-45 °C untuk CBR dan CBS, untuk CBE tidak ditetapkan, kadar air maksimum 0,3%, kadar asam lemak bebas maksimum 0,3 %, bilangan peroksida maksimum 3,0 mek O2/kg, bilangan iod untuk CBE, CBR dan CBS maksimum 40, 60 dan 20 gram I2/100 g berturut-turut.
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Akoh, C. C., & Moussata, C. O. (1998). Lipase‐catalyzed modification of borage oil: incorporation of capric and eicosapentaenoic acids to form structured lipids. Journal of the American Oil Chemists' Society, 75(6), 697-701.
AOCS. (2016). AOCS official method ca 2c-25, moisture and volatile matter-air oven method in official methods and recommended practices of the aocs 7th edition, Urbana, Illinois.
AOCS. (2016). AOCS official method ca 5a-40, free fatty acids in official methods and recommended practices of the aocs 7th edition, Urbana, Illinois.
Badan Standardisasi Nasional. (2009). SNI 3748:2009. Lemak kakao, Jakarta.
Balle J. (2006). Business area chocolate and confectionery fats. Capital Market Day, October 3, 2006.
Daulay, Nur Kholida. (2018). Penentuan kadar air, kadar kotoran, dan kadar asam lemak bebas (ALB) dari inti sawit produksi ptpn iv medan. departemen kimia. Universitas Sumatera Utara.
Famobuwa OE, Oloyede HO, Agbowuro AA. (2016). Chemical Changes in Crude Palm-Oil and Refined Palm Kernel-Oil Employed in Deep-Frying. The Pharmaceutical and Chemical Journal, 3(3):1-7.
Fuji Oil Europe. (2004). Confectionery. Retrieved from http://www.fujioileurope.com/Products/Confectionarv choccoat.htm [15 Juli 2012].
Gunstone, F. D. (2002). Food Applications of Lipids. Di dalam CC Akoh, and DB Min (eds). Food Lipids Chemisty, Nutrition, and Biotechnology. Revised and Expanded.
Hasibuan, H. A. (2009). Perolehan Kembali Nikel dari Katalis Nikel Terpakai (Spent Catalyst) Pasca Proses Hidrogenasi Minyak Sawit dengan Proses Pelindian (Leaching) Asam Sulfat (Master's thesis).
Idris, N. A., & Dian, N. L. H. M. (2005). Interesterified palm products as alternatives to hydrogenation. Asia Pacific journal of clinical nutrition, 14(4), 396-401.
ISO 6321:2002 .(2002). Animal and vegetable fats and oils -- Determination of melting point in open capillary tubes (slip point)
IUPAC. (1987). Standard method 2.301, preparation of fatty acid methyl ester, in standard methods for analysis of oils, fats and derivatives. 7th Edition, Blackwell, Oxford.
Lipp, M., Simoneau, C., Ulberth, F., Anklam, E., Crews, C., Brereton, P., ... & Wiedmaier, C. (2001). Composition of genuine cocoa butter and cocoa butter equivalents. Journal of Food Composition and analysis, 14(4), 399-408.
Lipp, M., & Anklam, E. (1998). Review on cocoa butter and alternatives for use in chocolate. Part B: Method of analysis. Journal of Food Chemistry, 62(1), 73-97.
Liu KJ, Chang HM, Liu KM. (2007). Enzymatic synthesis of cocoa butter analog through interesterification of lard and tristearin in supercritical carbon dioxide by lipase. Food Chemistry 100:1303-1311.
Marangoni, A. G., & Narine, S. S. (2002). Identifying key structural indicators of mechanical strength in networks of fat crystals. Food Research International, 35(10), 957-969.
Minifie, B. W. (1999). Chocolate, Cocoa and Confectionery : Science and Technology. Gaithersburg: Aspen Publishers, Inc.
Murano, P. S. (2003). Understanding food science and technology (No. 04; TP370, M8.). Thomson/Wadsworth.
Naik, B., & Kumar, V. (2014). Cocoa butter and its alterna-tives-a review. J Bioresource Eng Technol, 2, 1-11.
Lida, H. N., Sundram, K., Siew, W. L., Aminah, A., & Mamot, S. (2002). TAG composition and solid fat content of palm oil, sunflower oil, and palm kernel olein belends before and after chemical interesterification. Journal of the American Oil Chemists' Society, 79(11), 1137-1144.
O'brien, R. D. (2008). Fats and oils: formulating and processing for applications. CRC press.
Ojieh, G. C., Idokpesi, G. O., Eidangbe, G. O., Omage, K., & Oluba, O. M. (2009). Hydrogenation impairs the hypolipidemic and antioxidant effects of palm oil in rats. International Journal of Physical Sciences, 4(7), 407-411.
Osborn, H. T., & Akoh, C. C. (2002). Enzymatically modified beef tallow as a substitute for cocoa butter. Journal of food science, 67(7), 2480-2485.
Ovesen, L., Leth, T., & Hansen, K. (1998). Fatty acid composition and contents of trans monounsaturated fatty acids in frying fats, and in margarines and shortenings marketed in Denmark. Journal of the American Oil Chemists' Society, 75(9), 1079-1083.
Shamsudin, R., Mohamed, I. O., & Nooi, T. S. (2006). Rheological properties of cocoa butter substitute (CBS): effects of temperature and characteristics of fatty acids on viscocity. Journal of Food Lipids, 13(4), 402-410.
Shukla, V. K. (2005). Cocoa butter, cocoa butter equivalents, and cocoa butter substitutes. In Handbook of functional lipids (pp. 284-312). CRC Press.
Silalahi, J dan S.D.R. Tampubolon. (2012). Asam lemak trans dalam makanan dan pengaruhnya terhadap kesehatan. Jurnal.Teknol. dan Industri Pangan, XIII(2): 184-188.
Singh, D., Rezac, M. E., & Pfromm, P. H. (2009). Partial hydrogenation of soybean oil with minimal trans fat production using a Pt-decorated polymeric membrane reactor. Journal of the American Oil Chemists' Society, 86(1), 93.
SNI ISO 3961, Lemak dan minyak nabati dan hewani - Penentuan bilangan iod
Subbaiah, P. V., Subramanian, V. S., & Liu, M. (1998). Trans unsaturated fatty acids inhibit lecithin: cholesterol acyltransferase and alter its positional specificity. Journal of lipid research, 39(7), 1438-1447.
Sundram, K., Ismail, A., Hayes, K. C., Jeyamalar, R., & Pathmanathan, R. (1997). Trans (elaidic) fatty acids adversely affect the lipoprotein profile relative to specific saturated fatty acids in humans. The Journal of nutrition, 127(3), 514S-520S.
Sundram, K., & Basiron, Y. (2008). The trans fat dilemma: health VS functionality. Report of the Malaysian Palm Oil Council’s Official Report, 3.
Torbica, A., Jovanovic, O., & Pajin, B. (2006). The advantages of solid fat content determination in cocoa butter and cocoa butter equivalents by the Karlshamns method. European Food Research and Technology, 222(3-4), 385-391.
Undurraga, D., Markovits, A., & Erazo, S. (2001). Cocoa butter equivalent through enzymic interesterification of palm oil midfraction. Process biochemistry, 36(10), 933-939.
Wainwright, B. (1999). Specialty Fats and Oils. Di dalam N. Widlak (ed). Physical Properties of Fats, Oils and Emulsifiers. Am. Oil Chem. Soc. Press, Champaign, Illinois.
Wainwright, R. E. (1996). Oils and Fats in Confection. Di dalam YH Hui (ed.) Bailey’s Industrial Oil and Fat Products. Volume 3 Edible Oil and Fat Products: Products and Application Technology.
Wardlaw, G. M., & Insel, P. M. (1996). Perspectives in nutrition. Mosby College Pub.
[WHO] World Health Organization and [FAO] Agriculture Organization. (2010). Fats and fatty acids in human nutrition report and expert consultation. In Food and nutrition paper. Vol. 91. Food and Agriculture Organization of the United Nations
Zaidul, I. S. M., Norulaini, N. N., Omar, A. M., & Smith Jr, R. L. (2007). Blending of supercritical carbon dioxide (SC-CO2) extracted palm kernel oil fractions and palm oil to obtain cocoa butter replacers. Journal of Food Engineering, 78(4), 1397-1409.
Zhou, Y., & Hartel, R. W. (2006). Phase behavior of model lipid systems: Solubility of high-melting fats in low-melting fats. Journal of the American Oil Chemists' Society, 83(6), 505-511.
DOI: http://dx.doi.org/10.31153/js.v22i3.838
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